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Re: (ET) desulfator



Hello David
 
I have done a lot of testing exactly like you have requested for on AGM and Gel batteries. I had sent the following in a reply to another group about this same subject. Some of it repeats what you have said. Any way here is what I have concluded in using many different desulfators.
 
There are many false beliefs out there about restoring the capacity of lead acid batteries or resurrecting the dead. Mostly because of a few positive results that are not based on proper research testing methods. The claims of bringing dead batteries back or added capacity is used as one of the proofs these devices work.  I could write a 100 pages of all the different ideas and things I have come across on different web sites. The following is only about lead acid batteries from testing I have done.
 
The vast majority start off with a dead battery that will not accept a charge. The battery is charged with a pulse charger at a very low rate of amps but high voltage. Most of the time just about all dead batteries will come back with some life. The problems the battery had before such as a shorted cell or are just plain worn out are still there. If the battery was fine before and it was left in an uncharged state the best you can hope for is some level below what it was. If you take a brand new battery and leave it uncharged at zero volts. When you fully recharge it will be an unused damaged battery that diminished capacity. It will never be restored to a new battery.
 
Regardless of this many people believe they have equipment that can resurrect dead batteries or restore them. What is over looked is you can do this with just about all lead acid batteries by putting them on a regulated power supply or a float charger. If the battery should at 14.4 volts during charging you set the power supply to 14.4 and .5 amps and watch until the battery starts accepting a charge. This could take right away to a month at some point most all batteries will start taking a charge. When the battery starts accepting a charge a good float charger can finish the charging. It can take a very long time for a large battery to become fully charged. 
 
Many people are not aware their batteries are not really fully charged during regular use. Over charged batteries die but what appears to be saving the others is many times just bringing a battery to full charge. Some of these devices pull power from the battery and pulse it. The battery is supply the power to the desulfator. When the voltage goes down if you have it on a charger it will come on. This is why some of these devices are not recommend for vehicles that are not used daily. You would have battery at 10.5 volts until a charge was applied. What they do cause is your charging system to cycle.
 
So really what happens after using them is you have a battery that might show its full voltage but not the amp hours. If you cycle it a few times you might get a little increase in amp hours but no miracles. If the battery was in good shape before it might be a useable battery depending on use. One has to remember many applications do not involve the heavy demands of and EV. What we want in an EV battery is very demanding use. Even what we consider the bare minimum might be for someone else seem about as good as a new battery.
 
An AGM battery does pick up capacity after being cycled 5 or 10 times if it is done in a short time frame. This occurs if it has been maintained properly or left in a discharged state. Some of gains made with these devices that claim to be restoring your battery are just exercising it by discharging it and causing the charger to come on and recharge it. There is no real amp hour gain for an AGM it will go away when the battery sits.
 
All the results on any successful gains is falsely assumed to be from using these devices. Some of the web sites claiming they work use references that at first look legitimate. If you look further though you will find some use colleges or people that don't even exist. I was not the first to figure that out there was other posts on different sites that also made light of this. I still felt the need to full find out about these devices and the claims made.
 
I bought several different battery savers. The dead batteries were of the same make age and condition. At the beginning of the testing it appeared one or two of the devices might work based on Ah gains. It was only after the second or third cycle testing did the other batteries come up and many of them exceed the batteries revived with the battery savers. I repeated the tests over and over. This was with dozens of batteries and hundreds of hours of testing with and without using the desulfators. The results showed there was absolutely no measurable gain that can be credited to these devices. Someone who just does a battery or two would not learn this. They would go on thinking they were actually using a device that works.
 
 
I advise you to save your time and money do not buy any of these so called claimed battery saving devices. I highly recommend a regulated power supply you can buy on eBay for 40 to 100 dollars. If you want a really high powered one they cost more and may require 240 volts. Check the supply voltage some are three phase.
 
Don Blazer
 
 
In a message dated 2/17/2007 8:27:32 PM Pacific Standard Time, etpost drmm net writes:
On 17 Feb 2007 at 17:50, Neil Dennis wrote:

> My, My, that was quite a reaction (;-').

Sorry, I don't mean to be overbearing about this.  I've posted comments
about desulfators many times before here, though, and didn't really say
anything especially different this time (though I said it perhaps more
succinctly or more bluntly).

Let's try it this way.

Suppose you're down by the dock, cussing about your boat's battery.  It's a
few years old, and you're finding that it won't run the lights long enough. 
It's supposed to be a 120 amp hour battery, but you can use only about 30
amp hours before the lights start getting dim.  If you try to run the
trolling motor, the lights almost go out, and the motor barely runs.

I walk by and hear you complaining.  I stop and tell you, "You have a
sulfation problem. I have a gadget that will fix that.  This is a
desulfator.  It reverses sulfation.  It can recover some of your battery's
old zip - not all of it, mind you, but some.  Now, if you'd been using it
from the time the battery was new, your battery would still be almost like
new.  Use it on your next new battery, and when it's this old, it will still
be good enough to run your lights and motor."

It's a deal.  I leave with $69.95 in my pocket, and you have a nice little
black box.  It has an AC cord and a wire with clips for the battery. 
There's a little blinking LED on it. 

I told you to hook this black box up to the battery and leave it plugged in
for a few days, to get back some of the tired old battery's capacity.  And
when you get a new battery, you should use it for 12 to 24 hours about once
a month, to keep the battery in tip-top shape.

So you try it.  Lo and behold, you run it for 3 days and you now have 40 amp
hours.  You run it another 3 days and you have 50 amp hours.  Another week,
and you're up to 60!

Ah, but it doesn't last.  A month later you're back to 25 amp hours of
capacity.  So you bite the bullet and buy a new battery.  This time, you
hook up my gadget once a month for 24 hours, just as I suggested.  When this
battery is 3 years old, you have almost 100 of your original 120 amp hours
of capacity.  It works!

What did it do? 

In a brand new battery, not all the cells are exactly the same.  There's
always one that has a little less capacity.  Each time you charge the
battery, that's the last one to get full.  Sometimes it doesn't quite get
there.  If this happens too often, that cell really does begin to develop
permanent sulfation, but that's not what kills it. 

The capacity of your battery is determined by that weakest cell.  When that
weak cell goes dead, its electrolyte is essentially water.  Its internal
resistance goes way up.  Even if the other cells still have some charge
left, they can't push any decent amount of current through the resistance of
the dead cell.  So you can't get much useful work from the battery.  But
many times you keep trying to use the battery for a while.  It can still
light the lights for some time longer, even if dimly.

When you do this, you're forcing current through that dead cell.  This
charges it backwards.  This is called cell reversal, and it's very damaging.
Repeated reversal is what really kills the cell.  Its capacity takes a
dive, and now you have a 30 amp hour battery when it used to be 120 amp
hours.

When you connected my "desulfator," it forced current through the good cells
(in the right direction!) to give the bad one as much charge as it could
possibly hold. 

You also helped the battery yourself, just by taking an interest in it.  You
cycled it more often than you usually did.  Exercise for batteries is like
exercise for humans - it improves their stamina.  This helped to temporarily
build up its capacity.  That's why it rose from 1/4 to 1/2 its new capacity.

But then you went back to your old usage patterns, and the battery went back
to its old capacity.

In using my "desulfator" on the *new* battery, you were performing a regular
equalization on the battery.  This kept the inevitable weak cell fully
charged, preventing it from being reversed as frequently.  You kept the
battery fit and useful longer.

So I sold you a gadget that fixed your "sulfation problem."  I told you it
would reverse sulfation - and it did.  I told you it would give your battery
more capacity - and it did.  I told you it would keep a new battery fit
longer - and it did. You're happy, and I'm $69.95 richer.  What's the
problem?

What I sold you was a battery charger with a blinking LED.  Did I cheat you?
No.  I said it would reverse sulfation, and that's exactly what a battery
charger does - that's how a battery charges.  I said it would add some
capacity to your old battery, and an equalizing charge applied with a
battery charger will do that.  I said it would help a new battery last
longer, and equalization applied at the proper intervals will do that, too. 
Equalization brings up weak cells to get the maximum possible capacity out
of an old battery, and prevent damage to weak cells in a new battery.

I didn't make any claims about "crystal resonance," even though some
desulfator adherents try to do that.  Here's one example : "A desulfator
works by creating a resonance frequency that cause the sulfur ions in the
batteries to dissolve back into the electrolytic solution of the battery."

An electrochemist - an engineer who designs batteries - will tell you that
such claims are nonsense.  I suspect that the people who developed pulse
desulfators years ago found that they helped batteries, and they groped
around until they found something that seemed to explain (at least to their
satisfaction) what the gadgets were doing. 

Desulfators have a small but very avid and vocal corps of believers.  And
they are right, in a sense - the gadgets do work.  But so would a cheap
little trickle charger, for about one-third the price.  Or the charger you
already have. 

What I really sold you back there on the dock, for $69.95, was $19.95 worth
of charger and $50 worth of advice - that equalizing your battery regularly
would maximize its capacity and keep it healthy. 

But you could have gotten that advice for free - right here, in any number
of good battery books in the library or at the bookstore, or on the web. 

I sold you something you could have - should have - gotten for free.  Am I a
crook, or an entrepreneur?

For years I've been asking folks who sell desulfators, and those who are
sold on them, to perform a real test.  I want them to use two batches of
essentially identical batteries, applying the desulfator to half and a
decent equalizing charger to the other.  Treat the batteries exactly the
same except for what's charging them, and see if one group behaves
significantly differently.

I think that's a reasonable request.  It isn't 100% conclusive, but if their
desulfator is really better than an ordinary charger, it should show up in
statisically significant, consistently improved performance in the group
treated with the desulfator. 

So far no one has taken me up on it.  Any idea why not?


David Roden - Akron, Ohio, USA

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